BaMnSnS4 and BaCdGeS4: infrared nonlinear optical sulfides containing highly distorted motifs with centers of moderate electronegativity

Yang-Jie Lin; Run Ye; Long-Qi Yang; Xiao-Ming Jiang; Bin-Wen Liu; Hui-Yi Zeng; Guo-Cong Guo

doi:10.1039/C9QI00727J

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BaMnSnS₄ and BaCdGeS₄: infrared nonlinear optical sulfides containing highly distorted motifs with centers of moderate electronegativity†‡

Yang-Jie Lin,^a Run Ye,^a Long-Qi Yang,^a Xiao-Ming Jiang,*^a Bin-Wen Liu,^a Hui-Yi Zeng^a and Guo-Cong Guo

*^a

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* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
E-mail: xmjiang@fjirsm.ac.cn, gcguo@fjirsm.ac.cn
Fax: (+86)591-83714946

Abstract

IR NLO sulfides BaMnSnS₄ and BaCdGeS₄ exhibit significant SHG efficiencies (1.2 and 0.3AgGaS₂) with phase-matching behavior and high laser-induced damage thresholds (10 and 13AgGaS₂). Their strong SHG efficiencies mainly originate from SnS₄ and GeS₄ tetrahedra that are being modulated by highly distorted MnS₄ and CdS₄ tetrahedra.

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Article information

DOI: https://doi.org/10.1039/C9QI00727J
Article type: Research Article
Submitted: 17 Jun 2019
Accepted: 17 Jul 2019
First published: 19 Jul 2019

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Inorg. Chem. Front., 2019,6, 2365-2368

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BaMnSnS₄ and BaCdGeS₄: infrared nonlinear optical sulfides containing highly distorted motifs with centers of moderate electronegativity

Y. Lin, R. Ye, L. Yang, X. Jiang, B. Liu, H. Zeng and G. Guo, Inorg. Chem. Front., 2019, 6, 2365 DOI: 10.1039/C9QI00727J

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