Issue 7, 2019

Reactions of 2-aza-21-carbaporphyrin with aniline derivatives

Abstract

Regioselective azotization or bis(amination) products of the title porphyrinoid were achieved in one-pot one-step syntheses under mild conditions using a selection of aromatic amines and isoamyl nitrite or p-chloranil, respectively. Structures, tautomery, chirality as well as spectroscopic and redox properties of the new systems were discussed.

Graphical abstract: Reactions of 2-aza-21-carbaporphyrin with aniline derivatives

Associated articles

Supplementary files

Article information

Article type
Research Article
Submitted
07 Jan 2019
Accepted
11 Feb 2019
First published
12 Feb 2019

Org. Chem. Front., 2019,6, 908-918

Reactions of 2-aza-21-carbaporphyrin with aniline derivatives

D. Ren, B. Liu, X. Li, S. Koniarz, M. Pawlicki and P. J. Chmielewski, Org. Chem. Front., 2019, 6, 908 DOI: 10.1039/C9QO00024K

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