Issue 13, 2019
From the journal:

Organic Chemistry Frontiers

Rhodium-catalyzed alkenyl C–H functionalization with amides†

Yao Huang,a   Wen-Jing Pana  and  Zhong-Xia Wang ORCID logo *ab  

* Corresponding authors

a CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China
E-mail: zxwang@ustc.edu.cn

b Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, People's Republic of China

Abstract

Rhodium-catalyzed pyridyl-directed alkenyl C–H bond functionalization with aroyl- or acryl-amides was carried out. The reaction gave arylated or alkenylated alkenes in moderate to excellent yields in most cases and tolerates functional groups involving RO, Cl, F, CF3, CN, COOMe, C(O)Me, and NO2.

Graphical abstract: Rhodium-catalyzed alkenyl C–H functionalization with amides

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Article information

DOI
https://doi.org/10.1039/C9QO00489K
Article type
Research Article
Submitted
08 Apr 2019
Accepted
08 May 2019
First published
10 May 2019

Org. Chem. Front., 2019,6, 2284-2290

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Rhodium-catalyzed alkenyl C–H functionalization with amides

Y. Huang, W. Pan and Z. Wang, Org. Chem. Front., 2019, 6, 2284 DOI: 10.1039/C9QO00489K

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