Issue 14, 2019

Highly regio- and diastereoselective Cu-catalyzed hydroborylation and hydrosilylation of difluorocyclopropenes with B2pin2 and PhMe2Si–Bpin

Abstract

An efficient synthetic method for preparing trans-difluorocyclopropyl boronates and trans-difluorocyclopropyl silanes was easily achieved through a copper-catalyzed hydroborylation and hydrosilylation of difluorocyclopropenes with bis(pinacolato)diboron and silylboronate, respectively.

Graphical abstract: Highly regio- and diastereoselective Cu-catalyzed hydroborylation and hydrosilylation of difluorocyclopropenes with B2pin2 and PhMe2Si–Bpin

Supplementary files

Article information

Article type
Research Article
Submitted
30 Apr 2019
Accepted
31 May 2019
First published
31 May 2019

Org. Chem. Front., 2019,6, 2539-2543

Highly regio- and diastereoselective Cu-catalyzed hydroborylation and hydrosilylation of difluorocyclopropenes with B2pin2 and PhMe2Si–Bpin

X. Zhao, S. Xu, J. He, Y. Zhou and S. Cao, Org. Chem. Front., 2019, 6, 2539 DOI: 10.1039/C9QO00580C

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