Issue 11, 2019, Issue in Progress
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RSC Advances

Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins†

Dong Liang, ORCID logo ‡a   Yan Wang, ORCID logo ‡b   Sifan Wang,a   Chengkun Song,c   Yonghe Shi,a   Qinghao Liu, ORCID logo a   Hailin Zhu,a   Xia Li, ORCID logo a   Laishuan Liu*a  and  Na Zhu*d  

* Corresponding authors

a School of Chemical Engineering and Technology, North University of China, Taiyuan, People's Republic of China
E-mail: Liulaishuan@nuc.edu.cn

b College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, People's Republic of China

c School of Chemistry and Chemical Engineering, Southeast University, Nanjing, People's Republic of China

d College of Environment and Resource, Shanxi University, Taiyuan, People's Republic of China
E-mail: zhuna@sxu.edu.cn

Abstract

Chiral 1,2-diols with a high yield could be directly prepared from asymmetric di-hydroxylation of olefins via an eco-friendly and enduring catalyst, in which abundant “chiral pools” of polyoxometalate-ionic liquid were target-designed into the silicic framework (POM-ILS) and well stabilized in aqueous media.

Graphical abstract: Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins

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Article information

DOI
https://doi.org/10.1039/C8RA10544H
Article type
Paper
Submitted
25 Dec 2018
Accepted
31 Jan 2019
First published
19 Feb 2019
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2019,9, 6102-6106

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Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins

D. Liang, Y. Wang, S. Wang, C. Song, Y. Shi, Q. Liu, H. Zhu, X. Li, L. Liu and N. Zhu, RSC Adv., 2019, 9, 6102 DOI: 10.1039/C8RA10544H

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