Biosorption of anionic and cationic dyes via raw and chitosan oligosaccharide-modified Huai Flos Chrysanthemum at different temperatures

Abstract

Raw Huai Flos Chrysanthemum (HFC) and modified HFC (HFC@CO) were used for the first time as a biosorbent material to remove cationic dyes Malachite green (MG) and Crystal violet (CV), and anionic dyes Sunset yellow (SY), Lemon yellow (LY), and Carmine (CM), at different temperatures (5–50 °C). The highest removal rates (R) for dye adsorption were observed at low temperature (5 °C) and room temperature (20 °C). At high (500 mg L⁻¹) dye concentration, adsorption was completed within one minute, but the time required to reach adsorption equilibrium was longer than at the low (20 mg L⁻¹) concentration. The experimental data fitted very well to the Langmuir model and the values of the maximum adsorption capacity for SY, LY, CM, CV, and MG, were 481.41, 507.23, 141.78 mg g⁻¹, 526.32, and 769.23 mg L⁻¹, respectively. The adsorption data fit well to a pseudo-second-order kinetic model.