Issue 14, 2019, Issue in Progress

Homojunction and defect synergy-mediated electron–hole separation for solar-driven mesoporous rutile/anatase TiO2 microsphere photocatalysts

Abstract

The photocatalytic hydrogen evolution of TiO2 is deemed to be one of the most promising ways of converting solar energy to chemical energy; however, it is a challenge to improve the photo-generated charge separation efficiency and enhance solar utilization. Herein, black mesoporous rutile/anatase TiO2 microspheres with a homojunction and surface defects have been successfully synthesized by an evaporation-induced self-assembly, solvothermal and high-temperature surface hydrogenation method. The H500-BMR/ATM (HX-BMR/ATM, where X means the different hydrogen calcination temperatures) materials not only possess a mesoporous structure and relatively high specific surface area of 39.2 m2 g−1, but also have a narrow bandgap (∼2.87 eV), which could extend the photoresponse to the visible light region. They exhibit high photocatalytic hydrogen production (6.4 mmol h−1 g−1), which is much higher (approximately 1.8 times) than that of pristine mesoporous rutile/anatase TiO2 microspheres (3.58 mmol h−1 g−1). This enhanced photocatalytic hydrogen production property is attributed to the synergistic effect of the homojunction and surface defects in improving efficient electron–hole separation and high utilization of solar light. This work proposes a new approach to improve the performance of photocatalytic hydrogen production and probably offers a new insight into fabricating other high-performance photocatalysts.

Graphical abstract: Homojunction and defect synergy-mediated electron–hole separation for solar-driven mesoporous rutile/anatase TiO2 microsphere photocatalysts

Supplementary files

Article information

Article type
Paper
Submitted
24 Jan 2019
Accepted
01 Mar 2019
First published
08 Mar 2019
This article is Open Access
Creative Commons BY license

RSC Adv., 2019,9, 7870-7877

Homojunction and defect synergy-mediated electron–hole separation for solar-driven mesoporous rutile/anatase TiO2 microsphere photocatalysts

H. Li, B. Sun, F. Yang, Z. Wang, Y. Xu, G. Tian, K. Pan, B. Jiang and W. Zhou, RSC Adv., 2019, 9, 7870 DOI: 10.1039/C9RA00633H

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