Synergistic inhibition effect on the self-acceleration characteristics in the initial stage of methane/air explosion by CO2 and ultrafine water mist

Abstract

Cellular instability is responsible for the self-acceleration of a flame, and such acceleration might cause considerable damage. This paper presents an experimental study on the inhibition effect of CO₂ and an ultrafine water mist on the self-acceleration characteristics of a spherical flame in the initial stage of a 9.5% methane/air explosion in a constant volume combustion bomb. Results showed that insufficient water mist enhanced the self-acceleration of the spherical flame and the intensity of the explosion; nevertheless, the synergistic inhibition effect of CO₂ and ultrafine water mist prevented enhancement of the explosion and significantly mitigated the self-acceleration of spherical flames, which observably delayed the appearance time of a cellular flame, and reduced the flame propagation speed, overpressure and the mean rate of pressure rise, indicating that suppression of flame self-acceleration could effectively mitigate the damage from a methane/air explosion. The reason for the synergistic effect was a result of a combination of physical suppression and chemical suppression: due to the preferential diffusion dilution effect of CO₂, the initial flame speed was reduced, and the flame became thicker, which increased the evaporation time and quantity of droplets around the flame front, accordingly enhancing the cooling effect on the flame front. The increased flame thickness could withstand greater disturbance and inhibit the formation and development of a cellular flame. Meanwhile, CO₂ and H₂O can also reduce the concentration of active radicals (O, H and OH) and reduce the reaction rate and combustion rate of a methane/air explosion.