Facile preparation of low-cost HKUST-1 with lattice vacancies and high-efficiency adsorption for uranium

Abstract

In this work, we prepared HKUST-1 and HKUST-1 with lattice vacancies (HLV) using benzoic acid (BA) as a low-cost modulator to replace part of the traditional trimesic acid ligand (H₃BTC). The structure and morphology of the products were characterized by FTIR, XRD, SEM and XPS. The adsorption performance of the products for uranium from aqueous solutions was investigated. The results showed that the sorption of U(VI) on HKUST-1 and HLV agreed with the Langmuir isotherm model (R_HKUST-1² = 0.9867 and R_HLV² = 0.9828) and the maximum adsorption capacity was 430.98 mg g⁻¹ and 424.88 mg g⁻¹, respectively. According to kinetics studies, the adsorption fitted better with a pseudo-second-order model (R_HKUST-1² = 1.0000 and R_HLV² = 0.9978). The as-prepared adsorbents were used for the removal of uranium from real water samples as well. The results showed that HLV with lower cost is a promising adsorbent for uranium from aqueous solutions.