Synthesis and characterization of a novel, pH-responsive, bola-based dynamic crosslinked fracturing fluid

Abstract

Fracturing fluids are important media for hydraulic fracturing. Typically, the fluids are gelled using a polymeric gelling agent. Technological improvements over the years have focused primarily on improving the rheological performance, thermal stability, and the clean-up of crosslinked gels. In this study, novel supramolecular assembly of a low-damage fracturing fluid combining an ionic polymer gel (hydroxypropyl trimethylammonium chloride guar-cationic guar) and a bola surfactant fluid (bola carboxylate polypropylene glycol) is carried out and it is reported to have improved properties and special characteristics due to the synergistic effects of the dual systems, which are different from those of polymer gels and surfactant fluids. The viscosity of the fracturing fluid shows a sudden increase upon an increase in temperature and excellent self-assembly recovery after shearing. The fracturing fluid exhibits pH-responsive viscosity changes and low permeability impairment, due to the formation of a network structure and supramolecular microspheres at different pH values.