Issue 30, 2019
From the journal:

RSC Advances

Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes†

Tatsuki Nagata,a   Takeru Inoue,a   Xianjin Lin,a   Shinya Ishimoto,a   Seiya Nakamichi,a   Hideo Oka,a   Ryota Kondo,a   Takeyuki Suzukib  and  Yasushi Obora ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan
E-mail: obora@kansai-u.ac.jp

b Comprehensive Analysis Center, The Institute of Scientific and Industrial Research (ISIR), Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0057, Japan

Abstract

N,N-Dimethylformamide-stabilised Pd nanocluster (NC) catalysed cross-coupling reactions of hydrosilane/disilane have been investigated. In this reaction, the coupling reaction proceeds without ligands with low catalyst loading. N,N-Dimethylacetamide is a crucial solvent in these reactions. The solvent effect was considered by various techniques, such as transmission electron microscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The Pd NCs can be recycled five times under both hydrosilane and disilane reaction conditions.

Graphical abstract: Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes

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Article information

DOI
https://doi.org/10.1039/C9RA02895A
Article type
Paper
Submitted
17 Apr 2019
Accepted
28 May 2019
First published
03 Jun 2019
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2019,9, 17425-17431

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Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes

T. Nagata, T. Inoue, X. Lin, S. Ishimoto, S. Nakamichi, H. Oka, R. Kondo, T. Suzuki and Y. Obora, RSC Adv., 2019, 9, 17425 DOI: 10.1039/C9RA02895A

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