Rationally designed La and Se co-doped bismuth ferrites with controlled bandgap for visible light photocatalysis

Abstract

Development of efficient visible light photocatalysts for water purification and hydrogen production by water splitting has been quite challenging. The activities of visible light photocatalysts are generally controlled by the extent of absorption of incident light, band gap, exposure of catalyst surface to incident light and adsorbing species. Here, we have synthesized nanostructured, La and Se co-doped bismuth ferrite (BLFSO) nanosheets using double solvent sol–gel and co-precipitation methods. Structural analysis revealed that the La and Se co-doped BFO i.e. Bi_0.92La_0.08Fe_1−xSe_xO₃ (BLFSO) transformed from perovskite rhombohedral to orthorhombic phase. As a result of co-doping and phase transition, a significant decrease in the band gap from 2.04 eV to 1.76 eV was observed for BLFSO-50% (having Se doping of 50%) which requires less energy during transfer of electrons from the valence to the conduction band and ultimately enhances the photocatalytic activity. Moreover, upon increase in Se doping, the BLFSO morphology gradually changed from particles to nanosheets. Among various products, BLFSO-50% exhibited the highest photocatalytic activities under visible light owing to homogenous phase distribution, regular sheet type morphology and larger contact with dye containing solutions. In summary, La, Se co-doping is an effective approach to tune the electronic structure of photocatalysts for visible light photocatalysis.