Platinum nanoparticles decorating a biomass porous carbon nanocomposite-modified electrode for the electrocatalytic sensing of luteolin and application

Abstract

A sensitive electrochemical method was proposed for the determination of luteolin based on platinum (Pt) nanoparticles decorating a biomass porous carbon (BPC) composite-modified carbon ionic liquid electrode (CILE). For Pt–BPC/CILE, a pair of well-defined redox peaks of luteolin appeared with enhanced peak currents and the positive movement of peak potentials, proving the electrocatalytic activity of the Pt–BPC nanocomposite for redox reaction. The results can be ascribed to the porous structure of BPC, the catalytic activity of Pt nanoparticles and their synergistic effects. Electrochemical parameters were calculated via cyclic voltammetry and differential pulse voltammetry. The results showed that the oxidation peak currents increased linearly with the concentration of luteolin in the range from 0.008 to 100.0 μmol L⁻¹, with a detection limit of 2.6 ± 0.054 nmol L⁻¹. The analytical performance of this sensor was checked by the detection of luteolin contents in a real Duyiwei capsule sample with satisfactory results.