Issue 52, 2019

Ir(iii)-catalyzed thioether directed arene C–H alkenylation

Abstract

In this study, we demonstrate an Ir(III)-catalyzed thioether directed alkenylation of arene C–H bonds under mild reaction conditions. The selectivity for mono- or di-alkenylation is controlled by the concentration of alkene and oxidant loading. Various functional groups are tolerated, and moderate to good yields of alkenylated products are achieved.

Graphical abstract: Ir(iii)-catalyzed thioether directed arene C–H alkenylation

Supplementary files

Article information

Article type
Paper
Submitted
28 Aug 2019
Accepted
16 Sep 2019
First published
24 Sep 2019
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2019,9, 30134-30138

Ir(III)-catalyzed thioether directed arene C–H alkenylation

C. Li, X. Chen, R. Bao, D. Li, K. Zhang and D. Wang, RSC Adv., 2019, 9, 30134 DOI: 10.1039/C9RA06811B

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