Polymer network-derived nitrogen/sulphur co-doped three-dimensionally interconnected hierarchically porous carbon for oxygen reduction, lithium-ion battery, and supercapacitor

Abstract

Rational design and simple synthesis of carbon-based materials with high electrocatalytic activity are essential for their practical applications in electrochemical energy conversion and storage devices. Herein, we report the synthesis of nitrogen, sulfur co-doped three-dimensional interconnected hierarchically porous carbon (NSHPC) by zinc acetate assisted pyrolysis of polymer networks. The thus-synthesized NSHPC has a specific surface area of 1057 cm² g⁻¹ with the coexistence of micro- and meso-pores. As metal-free electrocatalyst, the NSHPC exhibits a promising activity towards oxygen reduction reactions as evidenced by the slightly negative shift of half-wave potential compared with commercial Pt/C catalyst. The assembled lithium ion battery using NSHPC as anode delivers the reversible capacity of 740 and 470 mA h g⁻¹ at current densities of 2 and 5 A g⁻¹ without performance decay after 1000 charge–discharge cycles. Moreover, the assembled supercapacitor using NSHPC as electrode has the capacitance of 203 F g⁻¹ at 1 A g⁻¹.