Adsorption and regeneration of leaf-based biochar for p-nitrophenol adsorption from aqueous solution

Abstract

As an environmentally friendly and low-cost adsorbent, biochar has great potential in wastewater treatment. This study investigated biochar derived from Platanus orientalis L. leaves (PLB) activated by KOH in terms of its capacity and reusability to adsorb p-nitrophenol (PNP). PLB had a large specific surface area and total pore volume, and exhibits good PNP removal with a maximal adsorption capacity of 622.73 mg g⁻¹ at 298 K. Batch experiments showed that PLB had a high PNP adsorption capacity under acidic conditions. Experimental results were well described by the pseudo-second-order kinetic model and the Langmuir adsorption isotherm model. The thermodynamic study showed that PNP adsorption was a spontaneously exothermic process, and increasing temperature was not conducive to adsorption. In addition, PNP adsorption was mainly attributed to hydrophobic interaction. The regeneration experiment showed that PLB had good reusability. After the fifth regeneration, the adsorption capacity of PLB still reached 557.05 mg g⁻¹. The deactivation of oxygen-containing functional groups and pore blockage were the causes for the decrease in adsorption capacity of the recycled PLB. Moreover, the biochar showed good adsorption efficiency and reusability, thereby suggesting its potential to serve as an efficient PNP adsorbent for wastewater treatment.