Improved light-harvesting and suppressed charge recombination by introduction of a nanograss-like SnO2 interlayer for efficient CdS quantum dot sensitized solar cells

Abstract

Quantum dot sensitized solar cell (QDSSC) performance is primarily limited by the recombination of charges at the interfaces of TiO₂/quantum dot (QD) sensitizer/electrolyte. Hence, blocking or suppressing the charge recombination is an essential requirement to elevate the QDSSC performance to the next level. To retard the charge recombination, herein, we propose the introduction of a SnO₂ nanograss (NG) interlayer on the surface of TiO₂ using the facile chemical bath deposition method. The SnO₂ NG interlayer not only inhibits the interfacial recombination processes in QDSSCs but also enhances the light-harvesting capability in generating more excitons. Hence, the TiO₂/SnO₂ NG/CdS QDSSCs can achieve the power conversion efficiency of 3.15%, which is superior to that of a TiO₂/CdS device (2.16%). Electrochemical impedance spectroscopy, open-circuit voltage decay and dark current analyses confirm that the recombination of charges at the photoanode/electrolyte interface is suppressed and the life time is improved by introducing the SnO₂ NG interlayer between the TiO₂ and CdS QD sensitizer.