Solvothermal synthesis of Mn-doped CsPbCl3 perovskite nanocrystals with tunable morphology and their size-dependent optical properties

Abstract

Doping metal ions in inorganic halide perovskite (CsPbX₃, X = Cl, Br, I) nanocrystals (NCs) endows the NCs with unique optical characteristics, and has thus attracted immense attention. However, controllable synthesis of high-quality doped perovskite NCs with tunable morphology still remains challenging. Here, we report a facile, effective and unified strategy for the controllable synthesis of Mn-doped CsPbCl₃ quantum dots (QDs) and nanoplatelets (NPLs) via a single-step solvothermal method. The incorporation of Mn²⁺ into CsPbCl₃ NCs introduces new broad photoluminescence (PL) emission from Mn²⁺ while maintaining the structure of host CsPbCl₃ NCs nearly intact. The PL intensity, emission peak position and size of the NCs can be accurately adjusted by altering the experimental parameters such as Mn-to-Pb feed ratio and reaction time. Especially, by changing the amount of ligands, Mn-doped CsPbCl₃ QDs, NPLs or their mixtures can be obtained. Both of the Mn-doped QDs and NPLs exhibit a size-dependent quantum confinement effect, which is confirmed by the relationship between the size of NCs and the exciton emission peaks. The solvothermal reaction condition plays an important role for the precise control of the structure, morphology and PL properties of the Mn-doped NCs. The as-prepared Mn-doped CsPbCl₃ NPLs with thickness down to ∼2 nm exhibit a PL quantum yield (PLQY) of more than 22%. This work introduces a new strategy for the controllable synthesis of Mn-doped perovskite NCs, which provides ideas for the in-depth study of the dope-and-grow process and can be extended to approaches of doping other metal ions.