Issue 13, 2019
From the journal:

Chemical Science

Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals†

Meng-En Sun,a   Yao Li,a   Xi-Yan Dongab  and  Shuang-Quan Zang ORCID logo *a  

* Corresponding authors

a College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China
E-mail: zangsqzg@zzu.edu.cn

b College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454000, China

Abstract

The [Mn2Cl9]5− mode of red emissive (C4NOH10)5Mn2Cl9·C2H5OH under thermal treatment will be cleaved into [MnCl4]2− in the green emissive (C4NOH10)2MnCl4 with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic–inorganic metal halide hybrids.

Graphical abstract: Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals

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Article information

DOI
https://doi.org/10.1039/C8SC04711A
Article type
Edge Article
Submitted
23 Oct 2018
Accepted
21 Feb 2019
First published
25 Feb 2019
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2019,10, 3836-3839

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Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals

M. Sun, Y. Li, X. Dong and S. Zang, Chem. Sci., 2019, 10, 3836 DOI: 10.1039/C8SC04711A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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