Novel bimetallic lanthanide metal–organic frameworks (Ln-MOFs) for colour-tuning through energy-transfer between visible and near-infrared emitting Ln3+ ions

Min Zeng; Chuanlang Zhan; Jiannian Yao

doi:10.1039/C8TC06445H

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Novel bimetallic lanthanide metal–organic frameworks (Ln-MOFs) for colour-tuning through energy-transfer between visible and near-infrared emitting Ln³⁺ ions†

Min Zeng,^ab Chuanlang Zhan

*^ab and Jiannian Yao^ab

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China

^b University of Chinese Academy of Sciences, Beijing, P. R. China
E-mail: clzhan@iccas.ac.cn

Abstract

A new family of isostructural bimetallic lanthanide metal–organic frameworks of M_1−xNd_xL₂ (M = Eu, Tb, and Dy, 0 < x < 1, L = 2,5-pyridinedicarboxylate) was designed for color-tuning. The controllable color-tuning in the red, green and blue regions has been achieved through energy transfer from visible emitting Ln³⁺ to near-infrared emitting Ln³⁺.

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Article information

DOI: https://doi.org/10.1039/C8TC06445H
Article type: Paper
Submitted: 21 Dec 2018
Accepted: 04 Feb 2019
First published: 05 Feb 2019

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J. Mater. Chem. C, 2019,7, 2751-2757

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Novel bimetallic lanthanide metal–organic frameworks (Ln-MOFs) for colour-tuning through energy-transfer between visible and near-infrared emitting Ln³⁺ ions

M. Zeng, C. Zhan and J. Yao, J. Mater. Chem. C, 2019, 7, 2751 DOI: 10.1039/C8TC06445H

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Journal of Materials Chemistry C