Issue 7, 2020
From the journal:

Chemical Communications

Revelation of the chiral recognition of alanine and leucine in an l-phenylalanine-based metal–organic framework†

Xue Ma,a   Yanhao Zhang,b   Yu Gao,a   Xinglin Li,a   Cuijie Wang,a   Hang Yuan,c   Ajuan Yu, ORCID logo *a   Shusheng Zhang ORCID logo c  and  Yuanyuan Cuid  

* Corresponding authors

a College of Chemistry, Key Laboratory of Molecular Sensing and Harmful Substances Detection Technology, Zhengzhou University, Kexue Avenue 100, Zhengzhou, Henan 450001, P. R. China
E-mail: yuajuan@zzu.edu.cn

b State Key Laboratory of Environmental and Biological Analysis, Department of Chemistry, Hong Kong Baptist University, Hong Kong, China

c Center of Advanced Analysis and Computational Science, Key Laboratory of Molecular Sensing and Harmful Substances Detection Technology, Zhengzhou University, Kexue Avenue 100, Zhengzhou, Henan 450001, P. R. China

d Shimadzu China Co. Ltd., Shanghai 200233, China

Abstract

As a proof-of-concept, an L-phenylalanine-based metal–organic framework Zn-MOF, namely [Zn2(L-Phe)2(bpe)2]n, was designed for experimentally revealing the chiral recognition mechanism of alanine and leucine by means of 13C CP MAS NMR spectroscopy, X-ray photoelectron spectroscopy and control experiments.

Graphical abstract: Revelation of the chiral recognition of alanine and leucine in an l-phenylalanine-based metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C9CC05912A
Article type
Communication
Submitted
30 Jul 2019
Accepted
16 Aug 2019
First published
17 Aug 2019

Chem. Commun., 2020,56, 1034-1037

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Revelation of the chiral recognition of alanine and leucine in an L-phenylalanine-based metal–organic framework

X. Ma, Y. Zhang, Y. Gao, X. Li, C. Wang, H. Yuan, A. Yu, S. Zhang and Y. Cui, Chem. Commun., 2020, 56, 1034 DOI: 10.1039/C9CC05912A

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