Issue 19, 2020
From the journal:

Chemical Communications

Photocatalytic and electrocatalytic hydrogen production using nickel complexes supported by hemilabile and non-innocent ligands†

Satoshi Inoue,a   Yin-Nan Yan,a   Katsunori Yamanishi, ORCID logo a   Yusuke Kataoka ORCID logo b  and  Tatsuya Kawamoto ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Kanagawa University, 2946 Tsuchiya, Hiratsuka, Japan
E-mail: kaw@kanagawa-u.ac.jp

b Department of Chemistry, Graduate School of Natural Science and Technology, Shimane University, 1060 Nishikawatsu, Matsue, Japan

Abstract

Nickel complexes with non-innocent ligands generated by one-electron reduction of octahedral Schiff base nickel(II) complexes with hemilabile ligands exhibited excellent catalytic activities of over 5000 TONs through a metal–ligand cooperation mechanism for hydrogen evolution from water under visible light irradiation.

Graphical abstract: Photocatalytic and electrocatalytic hydrogen production using nickel complexes supported by hemilabile and non-innocent ligands

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Article information

DOI
https://doi.org/10.1039/C9CC09568C
Article type
Communication
Submitted
10 Dec 2019
Accepted
10 Feb 2020
First published
12 Feb 2020

Chem. Commun., 2020,56, 2829-2832

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Photocatalytic and electrocatalytic hydrogen production using nickel complexes supported by hemilabile and non-innocent ligands

S. Inoue, Y. Yan, K. Yamanishi, Y. Kataoka and T. Kawamoto, Chem. Commun., 2020, 56, 2829 DOI: 10.1039/C9CC09568C

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