Isosmaragdyrin with an N3C2 core: stabilization of Rh(I) and organo-Pt(II) complexes

Mainak Das; Sangya Chitranshi; M. Murugavel; B. Adinarayana; Cherumuttathu H. Suresh; A. Srinivasan

doi:10.1039/D0CC00214C

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Isosmaragdyrin with an N₃C₂ core: stabilization of Rh(i) and organo-Pt(ii) complexes†

Mainak Das,^a Sangya Chitranshi,^a M. Murugavel,^a B. Adinarayana,^a Cherumuttathu H. Suresh

^b and A. Srinivasan

*^a

Author affiliations

* Corresponding authors

^a School of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNI, Bhubaneswar-752050, Odisha, India
E-mail: srini@niser.ac.in

^b Inorganic & Theoretical Chemistry Section, Chemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Trivandrum 695019, Kerala, India

Abstract

Isosmaragdyrin with an N₃C₂ core is successfully achieved by introducing a 2,6-di-m-phenylpyridine unit. The core is utilized to stabilize the Rh(I) ion in the N–Rh(I)–N bonding mode and the Pt(II) ion in the (N^C)N fashion to form an unsymmetrical pincer-type organometallic complex.

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Article information

DOI: https://doi.org/10.1039/D0CC00214C
Article type: Communication
Submitted: 09 Jan 2020
Accepted: 17 Feb 2020
First published: 18 Feb 2020

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Chem. Commun., 2020,56, 3551-3554

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Isosmaragdyrin with an N₃C₂ core: stabilization of Rh(I) and organo-Pt(II) complexes

M. Das, S. Chitranshi, M. Murugavel, B. Adinarayana, C. H. Suresh and A. Srinivasan, Chem. Commun., 2020, 56, 3551 DOI: 10.1039/D0CC00214C

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