Issue 29, 2020

Enhancing switchable dielectric property for crystalline supramolecular rotor compounds by adding polar components

Abstract

Two new compounds were obtained by assembling the [(2-methoxy-5-nitro-anilinium)(18-crown-6)]+ cation with non-polar PF6 and polar SO3CF3 anions, respectively. Benefiting from its polar anion, the SO3CF3 compound reveals a more significant dielectric switching behaviour during phase transition, demonstrating an effective strategy to enhance the dielectric property by adding polar components.

Graphical abstract: Enhancing switchable dielectric property for crystalline supramolecular rotor compounds by adding polar components

Supplementary files

Article information

Article type
Communication
Submitted
08 Feb 2020
Accepted
05 Mar 2020
First published
05 Mar 2020

Chem. Commun., 2020,56, 4114-4117

Enhancing switchable dielectric property for crystalline supramolecular rotor compounds by adding polar components

R. Huang, X. Chen, Z. Xiao, D. Liu, W. Zhang and X. Chen, Chem. Commun., 2020, 56, 4114 DOI: 10.1039/D0CC01026J

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