Issue 37, 2020
From the journal:

Chemical Communications

Highly selective hydrosilylation of equilibrating allylic azides†

Ruzhang Liu, ORCID logo *a   Zhen Wei,a   Juan Wang,a   Yongmei Liua  and  Huaiguo Xuea  

* Corresponding authors

a College of Chemistry & Chemical Engineering, Yangzhou University, 180 Siwangting Rd., Yangzhou 225002, China
E-mail: liurzh@yzu.edu.cn

Abstract

The Pt-catalyzed hydrosilylation of equilibrating allylic azides is reported. The reaction provides only one out of four possible hydrosilylation products in good yields and with very high chemoselectivity (alk-1-ene vs. alk-2-ene), regioselectivity (linear vs. branched), and excellent functional group tolerance.

Graphical abstract: Highly selective hydrosilylation of equilibrating allylic azides

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Article information

DOI
https://doi.org/10.1039/D0CC01316A
Article type
Communication
Submitted
19 Feb 2020
Accepted
27 Mar 2020
First published
27 Mar 2020

Chem. Commun., 2020,56, 5038-5041

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Highly selective hydrosilylation of equilibrating allylic azides

R. Liu, Z. Wei, J. Wang, Y. Liu and H. Xue, Chem. Commun., 2020, 56, 5038 DOI: 10.1039/D0CC01316A

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