Issue 56, 2020
From the journal:

Chemical Communications

Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(ii) carbido complex†

Harrison J. Barnett ORCID logo a  and  Anthony F. Hill ORCID logo *a  

* Corresponding authors

a Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, Australia
E-mail: a.hill@anu.edu.au

Abstract

The reaction of [Rh2(μ-C)Cl2(PPh3)4] with 1,1′-bis(diphenylphosphino)ferrocene (dppf) affords the μ-carbido complex [Rh2(μ-C)Cl2(μ-dppf)2] which reacts with PhICl2 to provide a diamagnetic dirhodium(II) carbido complex [Rh2(μ-C)Cl4(μ-dppf)2].

Graphical abstract: Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(ii) carbido complex

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Article information

DOI
https://doi.org/10.1039/D0CC02349C
Article type
Communication
Submitted
01 Apr 2020
Accepted
27 May 2020
First published
04 Jun 2020

Chem. Commun., 2020,56, 7738-7740

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Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(II) carbido complex

H. J. Barnett and A. F. Hill, Chem. Commun., 2020, 56, 7738 DOI: 10.1039/D0CC02349C

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