Issue 50, 2020
From the journal:

Chemical Communications

A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii)†

Moya A. Hay, ORCID logo a   Arup Sarkar, ORCID logo b   Gavin A. Craig, ORCID logo ‡a   Katie E. R. Marriott,a   Claire Wilson, ORCID logo a   Gopalan Rajaraman ORCID logo *b  and  Mark Murrie ORCID logo *a  

* Corresponding authors

a School of Chemistry, University of Glasgow, University Avenue, Glasgow, UK
E-mail: mark.murrie@glasgow.ac.uk

b Department of Chemistry, Institute of Technology Bombay, Powai, Mumbai, Maharashtra, India
E-mail: rajaraman@chem.iitb.ac.in

Abstract

The first trigonal bipyramidal Fe(II) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D = −27.5 cm−1) and a pseudo-D3h symmetry at the Fe(II) centre, as investigated through ab initio and magnetic studies.

Graphical abstract: A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii)

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Article information

DOI
https://doi.org/10.1039/D0CC02382E
Article type
Communication
Submitted
02 Apr 2020
Accepted
06 May 2020
First published
06 May 2020
This article is Open Access
Creative Commons BY license

Chem. Commun., 2020,56, 6826-6829

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A large axial magnetic anisotropy in trigonal bipyramidal Fe(II)

M. A. Hay, A. Sarkar, G. A. Craig, K. E. R. Marriott, C. Wilson, G. Rajaraman and M. Murrie, Chem. Commun., 2020, 56, 6826 DOI: 10.1039/D0CC02382E

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