Constructing multi-cluster copper(I) halides using conformationally flexible ligands

Muxin Yu; Caiping Liu; Shengchang Li; Yunfang Zhao; Jiangquan Lv; Zhu Zhuo; Feilong Jiang; Lian Chen; Yunlong Yu; Maochun Hong

doi:10.1039/D0CC02472D

Constructing multi-cluster copper(i) halides using conformationally flexible ligands†

Muxin Yu,^ab Caiping Liu,^b Shengchang Li,^b Yunfang Zhao,^b Jiangquan Lv,^a Zhu Zhuo,^bc Feilong Jiang,^b Lian Chen,

*^b Yunlong Yu*^a and Maochun Hong

^b

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* Corresponding authors

^a Organic Optoelectronics Engineering Research Centre of Fujian's Universities, College of Electronics and Information Science, Fujian Jiangxia University, Fuzhou, Fujian, China
E-mail: ylyu@fjjxu.edu.cn

^b State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: cl@fjirsm.ac.cn, hmc@fjirsm.ac.cn

^c Xiamen Institute of Rare Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen, Fujian, China

Abstract

Three unprecedented multi-cluster copper(I) halides (MCCHs) have been assembled using conformationally flexible ligands. Further explorations demonstrate that the conformational compliance of the ligands may be the key to trap and stabilize the various copper(I)-halide clusters in one system, which opens a new way for the construction of multi-Cu(I)-cluster complexes. Moreover, the MCCHs show distinctive temperature-dependent photoluminescence.

Chemical Communications

Constructing multi-cluster copper(i) halides using conformationally flexible ligands†

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Constructing multi-cluster copper(I) halides using conformationally flexible ligands

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