Manganese catalysed ester reduction using ethanol as a hydrogen transfer agent in place of dihydrogen is reported. High yields can be achieved for a range of substrates using 1 mol% of a Mn(I) catalyst, with an alkoxide promoter. The catalyst is derived from a tridentate P,N,N ligand.
C. L. Oates, M. B. Widegren and M. L. Clarke, Chem. Commun., 2020, 56, 8635 DOI: 10.1039/D0CC02598D
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