Issue 67, 2020
From the journal:

Chemical Communications

Two-step gas adsorption induced by the transmetallation in a two-dimensional metal–organic framework†

Hye Jeong Park,a   Jongbum Oh,a   Jiwon Kima  and  Jaheon Kim ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Soongsil University, Seoul 06978, Republic of Korea
E-mail: jaheon@ssu.ac.kr

Abstract

Transmetallation or replacement of Zn2+ ions with Cu2+ ions in a two-dimensional metal–organic framework, Zn3(TCPB)2(H2O)2 (H3TCPB = 1,3,5-tri(4-carboxyphenoxy)benzene), gives rise to additional gas adsorption, where the additional adsorption amount linearly depends on the degree of the transmetallation.

Graphical abstract: Two-step gas adsorption induced by the transmetallation in a two-dimensional metal–organic framework

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Article information

DOI
https://doi.org/10.1039/D0CC03007D
Article type
Communication
Submitted
26 Apr 2020
Accepted
16 Jul 2020
First published
16 Jul 2020

Chem. Commun., 2020,56, 9727-9730

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Two-step gas adsorption induced by the transmetallation in a two-dimensional metal–organic framework

H. J. Park, J. Oh, J. Kim and J. Kim, Chem. Commun., 2020, 56, 9727 DOI: 10.1039/D0CC03007D

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