Issue 63, 2020
From the journal:

Chemical Communications

Conventional and unconventional alkyne activations by Ru and Os for unprecedented dimetalated quinolizinium complexes†

Chi-Fung Yeung, ORCID logo ‡ab   Lai-Hon Chung, ORCID logo ‡a   Sheung-Ying Tse, ORCID logo a   Hau-Lam Shek, ORCID logo a   Man-Kit Tse, ORCID logo a   Shek-Man Yiu ORCID logo a  and  Chun-Yuen Wong ORCID logo *ab  

* Corresponding authors

a Department of Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong SAR
E-mail: acywong@cityu.edu.hk

b State Key Laboratory of Terahertz and Millimeter Waves City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong SAR

Abstract

Two types of unexpected quinolizinium complexes were obtained from the reactions between pyridine-functionalized propargylic alcohol HC[triple bond, length as m-dash]CC(OH)(Ph)(CH2(2-py)) (L1) and cis-[M(L^L)2Cl2] (M = Ru, Os; L^L = 1,1-bis(diphenylphosphino)methane (dppm), 2,2′-bipyridine (bpy)). Their molecular structures revealed that L1 can be activated by Ru and Os via the conventional “vinylidene-involving” or unconventional “non-vinylidene-involving” pathways.

Graphical abstract: Conventional and unconventional alkyne activations by Ru and Os for unprecedented dimetalated quinolizinium complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0CC03480K
Article type
Communication
Submitted
15 May 2020
Accepted
01 Jul 2020
First published
10 Jul 2020

Chem. Commun., 2020,56, 8908-8911

Permissions

Request permissions

Conventional and unconventional alkyne activations by Ru and Os for unprecedented dimetalated quinolizinium complexes

C. Yeung, L. Chung, S. Tse, H. Shek, M. Tse, S. Yiu and C. Wong, Chem. Commun., 2020, 56, 8908 DOI: 10.1039/D0CC03480K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements