Match–mismatch effects in two-fold transfer of chirality within a Möbius metallo-receptor

Abstract

Two-fold transfer of chirality has been investigated in a Möbius Zn(II) hexaphyrin metallo-receptor able to bind simultaneously two different chiral molecules. Match/mismatch effects influence the dynamic stereoselective twisting of the π-system, and allow tuning of the induced chiroptical activity. Such allosteric control is attractive for building chirality sensing systems.