Issue 69, 2020
From the journal:

Chemical Communications

A large room-temperature entropy change in a new hybrid ferroelastic with an unconventional bond-switching mechanism†

Wei-Jian Xu, ORCID logo ab   Ying Zeng,a   Wei Yuan,a   Wei-Xiong Zhang ORCID logo *a  and  Xiao-Ming Chen ORCID logo a  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: zhangwx6@mail.sysu.edu.cn

b Department of Chemistry & CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal

Abstract

We showed a reversible bond-switching ferroelastic phase transition at near room temperature in a novel organic–inorganic hybrid, (Me3NNH2)2[Co(CN)6Na(H2O)], to afford a latent heat of 43.7 kJ kg−1 and a large entropy change of 146 J K−1 kg−1.

Graphical abstract: A large room-temperature entropy change in a new hybrid ferroelastic with an unconventional bond-switching mechanism

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Article information

DOI
https://doi.org/10.1039/D0CC04092D
Article type
Communication
Submitted
11 Jun 2020
Accepted
17 Jul 2020
First published
17 Jul 2020

Chem. Commun., 2020,56, 10054-10057

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A large room-temperature entropy change in a new hybrid ferroelastic with an unconventional bond-switching mechanism

W. Xu, Y. Zeng, W. Yuan, W. Zhang and X. Chen, Chem. Commun., 2020, 56, 10054 DOI: 10.1039/D0CC04092D

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