Issue 73, 2020

Hexagonal ordering of racemic Ni(ii) complexes in the interlayer space of a clay mineral

Abstract

The molecular arrangement of racemic [Ni(phen)3]2+ complexes in the interlayer space of montmorillonite was investigated using X-ray diffraction measurements. When the amount of the adsorbed complexes exceeded the cation exchange capacity, they were found to form a double-molecular layer with the 2D hexagonal arrangement in the interlayer space.

Graphical abstract: Hexagonal ordering of racemic Ni(ii) complexes in the interlayer space of a clay mineral

Supplementary files

Article information

Article type
Communication
Submitted
21 Jul 2020
Accepted
31 Jul 2020
First published
06 Aug 2020

Chem. Commun., 2020,56, 10670-10673

Hexagonal ordering of racemic Ni(II) complexes in the interlayer space of a clay mineral

J. Yoshida, K. Tateyama, H. Yuge and M. Hara, Chem. Commun., 2020, 56, 10670 DOI: 10.1039/D0CC04977H

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