Issue 94, 2020
From the journal:

Chemical Communications

Porous Li-MOF as a solid-state electrolyte: exploration of lithium ion conductivity through bio-inspired ionic channels†

Karabi Nath, ORCID logo a   Abdulla Bin Rahaman,b   Rajib Moi, ORCID logo a   Kartik Maity ORCID logo a  and  Kumar Biradha ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology, Kharagpur-721302, India
E-mail: kbiradha@chem.iitkgp.ernet.in
Tel: +91-3222-283346

b Department of Physics, Indian Institute of Technology, Kharagpur-721302, India

Abstract

A rarely porous Li-MOF (Li-AOIA) with surface area of 605 m2 g−1 was employed for the formation of an emerging class of solid-state lithium ion electrolytes. Infiltration of LiBF4 into Li-AOIA afforded Li-AOIA@BF4 with ionic conductivity of 1.09 × 10−5 S cm−1 at room temperature and an activation energy of 0.18 eV.

Graphical abstract: Porous Li-MOF as a solid-state electrolyte: exploration of lithium ion conductivity through bio-inspired ionic channels

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Article information

DOI
https://doi.org/10.1039/D0CC05728B
Article type
Communication
Submitted
24 Aug 2020
Accepted
03 Nov 2020
First published
03 Nov 2020

Chem. Commun., 2020,56, 14873-14876

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Porous Li-MOF as a solid-state electrolyte: exploration of lithium ion conductivity through bio-inspired ionic channels

K. Nath, A. Bin Rahaman, R. Moi, K. Maity and K. Biradha, Chem. Commun., 2020, 56, 14873 DOI: 10.1039/D0CC05728B

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