Dielectric and gas adsorption/desorption properties of x-Li(Pc) having one-dimensional channels surrounded by Pc˙− columns

Miki Nishi; Norihisa Hoshino; Shin-ichiro Noro; Hitoshi Fujimoto; Tomoyuki Akutagawa; Masaki Matsuda

doi:10.1039/D0CE01157F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Dielectric and gas adsorption/desorption properties of x-Li(Pc) having one-dimensional channels surrounded by Pc˙⁻ columns†

Miki Nishi,^a Norihisa Hoshino,

^b Shin-ichiro Noro,

^c Hitoshi Fujimoto,^a Tomoyuki Akutagawa

*^b and Masaki Matsuda

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan
E-mail: masaki@kumamoto-u.ac.jp

^b Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan
E-mail: akutagawa@tohoku.ac.jp

^c Faculty of Environmental Earth Science, Hokkaido University, N10W5, Sapporo 060-0810, Japan

Abstract

A one-dimensional channel system x-Li(Pc), composed of π-radical Pc˙⁻, was investigated. Crystal structure analysis revealed that this channel surrounded by Li(Pc) columns is flexible, and gas adsorption/desorption measurements showed selective adsorption/desorption properties. Along with Li⁺ motion, specific dielectric properties induced by a guest species within the channel were also observed.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D0CE01157F
Article type: Communication
Submitted: 07 Aug 2020
Accepted: 29 Sep 2020
First published: 27 Oct 2020

Download Citation

CrystEngComm, 2020,22, 7528-7531

Permissions

Request permissions

Dielectric and gas adsorption/desorption properties of x-Li(Pc) having one-dimensional channels surrounded by Pc˙⁻ columns

M. Nishi, N. Hoshino, S. Noro, H. Fujimoto, T. Akutagawa and M. Matsuda, CrystEngComm, 2020, 22, 7528 DOI: 10.1039/D0CE01157F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm