Issue 23, 2020

Enormous enhancement of p-orbital magnetism and band gap in the lightly doped carbyne

Abstract

This paper presents a path to tailor adapted magnetic and electronic properties in carbyne. Although p-orbital magnetism is generally much weaker than d-orbital magnetism, we demonstrate that the charge fluctuation of the free radical electrons triggered by a time-varying electric dipole moment leads to enormous p-orbital magnetism. By introducing 25% arsenic and 12.5% fluorine into the monoatomic carbon chain, the magnetic moment of the arsenic atom reaches 2.9 μB, which is ∼1.3 times stronger than magnetic moment of bulk Fe. This magnetically optimized carbyne composite carries an exchange–correlation energy of 22 meV (∼270 K). On the other hand, we convert the carbyne (in beta-form) from metallic to a semiconducting state by using anionic dopants. After doping 12.5% nitrogen and 12.5% oxygen into the beta-carbyne, the semiconducting gap of this composite is optimized at 1.6 eV, which is 1.4 times larger than the band gap of bulk silicon.

Graphical abstract: Enormous enhancement of p-orbital magnetism and band gap in the lightly doped carbyne

Article information

Article type
Paper
Submitted
28 Apr 2020
Accepted
27 May 2020
First published
27 May 2020

Phys. Chem. Chem. Phys., 2020,22, 12996-13001

Enormous enhancement of p-orbital magnetism and band gap in the lightly doped carbyne

C. H. Wong, R. Lortz and A. F. Zatsepin, Phys. Chem. Chem. Phys., 2020, 22, 12996 DOI: 10.1039/D0CP02274H

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