Issue 14, 2020

Synthesis and study of Fe → Pd interactions in unsymmetric Pd(ii) complexes with phosphinoferrocene guanidine ligands

Abstract

Readily available phosphinoferrocene guanidines coordinate Pd(II) as P,N-chelating or κ3P,N,Fe-bound ligands. As the latter, they give rise to the first donor-asymmetric complexes featuring Fe–Pd dative bonds, which were studied using direct (spectroscopic and electrochemical) methods and theoretical (DFT) approaches.

Graphical abstract: Synthesis and study of Fe → Pd interactions in unsymmetric Pd(ii) complexes with phosphinoferrocene guanidine ligands

Supplementary files

Article information

Article type
Communication
Submitted
04 Mar 2020
Accepted
16 Mar 2020
First published
16 Mar 2020

Dalton Trans., 2020,49, 4225-4229

Synthesis and study of Fe → Pd interactions in unsymmetric Pd(II) complexes with phosphinoferrocene guanidine ligands

O. Bárta, R. Gyepes, I. Císařová, A. Alemayehu and P. Štěpnička, Dalton Trans., 2020, 49, 4225 DOI: 10.1039/D0DT00812E

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