A novel geometric structure of a nanocluster with an irregular kernel: Ag30Cu14(TPP)4(SR)28

Jiale Li; Hao Li; Haizhu Yu; Jinsong Chai; Qinzhen Li; Yongbo Song; Zhongjie Zhang; Manzhou Zhu

doi:10.1039/D0DT01142H

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A novel geometric structure of a nanocluster with an irregular kernel: Ag₃₀Cu₁₄(TPP)₄(SR)₂₈†

Jiale Li,^a Hao Li,^a Haizhu Yu,^a Jinsong Chai,^a Qinzhen Li,^a Yongbo Song,^a Zhongjie Zhang

*^a and Manzhou Zhu

*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials. Anhui University, Hefei, Anhui, People's Republic of China

^b Key Laboratory of Structure and Functional Regulation of Hybrid Materials (Anhui University), Ministry of Education, Institute of Physical Science and Information Technology, China
E-mail: zhangzj06@ahu.edu.cn, zmz@ahu.edu.cn

Abstract

Here, we report a bi-ligand protected bimetallic nanocluster Ag₃₀Cu₁₄(TPP)₄(SR)₂₈. It is composed of an Ag₂₇ kernel and Ag₃Cu₁₄(TPP)₄(SR)₂₈ shell. Typically, the metal atoms are arranged irregularly. Both the core and shell exhibit the characteristics of C₂-symmetry.

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Article information

DOI: https://doi.org/10.1039/D0DT01142H
Article type: Communication
Submitted: 26 Mar 2020
Accepted: 21 May 2020
First published: 22 May 2020

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Dalton Trans., 2020,49, 7684-7687

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A novel geometric structure of a nanocluster with an irregular kernel: Ag₃₀Cu₁₄(TPP)₄(SR)₂₈

J. Li, H. Li, H. Yu, J. Chai, Q. Li, Y. Song, Z. Zhang and M. Zhu, Dalton Trans., 2020, 49, 7684 DOI: 10.1039/D0DT01142H

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