A stable dysprosium(iii) complex with a terminal fluoride ligand showing high resolution luminescence and slow magnetic relaxation

Abstract

An air-stable dysprosium(III) complex, [C(NH₂)₃]₄[DyF(piv)₄](piv)₂ (piv = pivalate), with a terminal fluoride ligand protected by forming extensive hydrogen bonds with peripheral guanidiniums has been isolated. Though the magnetic data failed to determine the energy barrier for the magnetic reversal (U_eff) accurately, the fine emission spectrum of the ⁴F_9/2 → ⁶H_15/2 transition at 4.2 K and ab initio calculations reveal that the U_eff is about 376(20) K, which is among the highest for high-coordinate (coordination numbers ≥ 9) lanthanide mononuclear magnets.