Issue 30, 2020
From the journal:

Dalton Transactions

Isostructural mesoporous ionic crystals as a tunable platform for acid catalysis†

Yuto Shimoyama, ORCID logo a   Zhewei Weng,a   Naoki Ogiwara, ORCID logo a   Takashi Kitao, ORCID logo bc   Yuji Kikukawa ORCID logo d  and  Sayaka Uchida ORCID logo *a  

* Corresponding authors

a Department of Basic Science, School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan
E-mail: csayaka@g.ecc.u-tokyo.ac.jp

b Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

c Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan

d Department of Chemistry, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa city, Ishikawa 920-1192, Japan

Abstract

Eleven isostructural mesoporous ionic crystals (meso–PICs) are synthesized. The initial activities of the Barbier-Grignard reaction, which is a typical C–C bond formation reaction, catalyzed by the meso-PICs are dependent on the acid dissociation constant of the aqua ions of Mn+ and the types of polyoxometalates, which construct the meso-PICs.

Graphical abstract: Isostructural mesoporous ionic crystals as a tunable platform for acid catalysis

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0DT01202E
Article type
Communication
Submitted
01 Apr 2020
Accepted
04 Jun 2020
First published
05 Jun 2020

Dalton Trans., 2020,49, 10328-10333

Permissions

Request permissions

Isostructural mesoporous ionic crystals as a tunable platform for acid catalysis

Y. Shimoyama, Z. Weng, N. Ogiwara, T. Kitao, Y. Kikukawa and S. Uchida, Dalton Trans., 2020, 49, 10328 DOI: 10.1039/D0DT01202E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements