MnI complex redox potential tunability by remote lewis acid interaction

Anandi Srinivasan; Jesús Campos; Nicolas Giraud; Marc Robert; Orestes Rivada-Wheelaghan

doi:10.1039/D0DT02467H

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Mn^I complex redox potential tunability by remote lewis acid interaction†

Anandi Srinivasan,^a Jesús Campos,

^b Nicolas Giraud,

^c Marc Robert

^ad and Orestes Rivada-Wheelaghan

*^a

Author affiliations

* Corresponding authors

^a Université de Paris, Laboratoire d'Electrochimie Moléculaire, CNRS, F-75006 Paris, France
E-mail: orestes.rivada@u-paris.fr

^b Instituto de Investigaciones Químicas (IIQ), Consejo Superior de Investigaciones Científicas (CSIC) and University of Sevilla, Avenida Américo Vespucio 49, 41092 Sevilla, Spain

^c Université de Paris, Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques, CNRS, F-75006 Paris, France

^d Institut Universitaire de France (IUF), F-75005 Paris, France

Abstract

In this work we provide direct experimental evidence on the correlation of remote interactions between a newly synthesized Mn^I-complex (1) and different alkali cations with redox potential tuning. Furthermore we report the electrochemical behavior of 1 towards carbon dioxide, including the effects of added alkali salts using cyclic voltammetry.

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Article information

DOI: https://doi.org/10.1039/D0DT02467H
Article type: Communication
Submitted: 13 Jul 2020
Accepted: 23 Jul 2020
First published: 24 Jul 2020
This article is Open Access

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Dalton Trans., 2020,49, 16623-16626

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Mn^I complex redox potential tunability by remote lewis acid interaction

A. Srinivasan, J. Campos, N. Giraud, M. Robert and O. Rivada-Wheelaghan, Dalton Trans., 2020, 49, 16623 DOI: 10.1039/D0DT02467H

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