Issue 46, 2020
From the journal:

Dalton Transactions

One-dimensional DABCO hydrogen-bonding chain in a hexagonal channel of magnetic [Ni(dmit)2]†

Simin Li,a   Kiyonori Takahashi, ORCID logo *ab   Ichiro Hisaki, ORCID logo c   Kenta Kokado ORCID logo abd  and  Takayoshi Nakamura*ab  

* Corresponding authors

a Graduate School of Environmental Science, Hokkaido University, N10W5, Kita-ku, Sapporo 060-0810, Japan
E-mail: ktakahashi@es.hokudai.ac.jp, tnaka@es.hokudai.ac.jp

b Research Institute for Electronic Science (RIES), Hokkaido University, N20W10, Kita-ku, Sapporo, Japan

c Graduate School of Engineering Science, Osaka University, 1-3, Machikaneyama, Toyonaka, Osaka, Japan

d JST-PRESTO, Honcho 4โ€“1-8, Kawaguchi, Saitama 332-0012, Japan

Abstract

Crystals of (HDABCO+)9(DABCO)[Ni(dmit)2]9ยท6CH3CN were shown to have a space group of R[3 with combining macron], a hexapetal flower-like channel of [Ni(dmit)2] anions, and a one-dimensional hydrogen bonding chain composed of protonated DABCO and CH3CN molecules. The crystals display antiferromagnetic and ferromagnetic interactions within and between hexamers, respectively, whereas the flexible DABCO-CH3CN array shows dielectric relaxation.

Graphical abstract: One-dimensional DABCO hydrogen-bonding chain in a hexagonal channel of magnetic [Ni(dmit)2]

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0DT03386C
Article type
Paper
Submitted
30 Sep 2020
Accepted
04 Nov 2020
First published
05 Nov 2020

Dalton Trans., 2020,49, 16772-16777

Author version available


Download author version (PDF)

Permissions

Request permissions

One-dimensional DABCO hydrogen-bonding chain in a hexagonal channel of magnetic [Ni(dmit)2]

S. Li, K. Takahashi, I. Hisaki, K. Kokado and T. Nakamura, Dalton Trans., 2020, 49, 16772 DOI: 10.1039/D0DT03386C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements