Issue 9, 2020

Synthesis and characterization of Cu3SbS4 thin films grown by co-sputtering metal precursors and subsequent sulfurization

Abstract

Cu3SbS4 (famatinite) thin films were synthesized using a two-step process: Cu and Sb metals were first deposited by RF magnetron sputtering, followed by subsequent sulfurization. The influence of metal precursor ratio, sulfurization temperature and time on surface morphology, composition, and structural and optical properties was systematically investigated. X-ray diffraction and Raman analysis revealed the formation of Cu3SbS4 phase thin films, where the crystallinity and phase purity improve with sulfurization temperature. Synthesis at a process temperature of 425 °C gave phase-pure Cu3SbS4 thin film with uniform surface morphology, whereas secondary phases were formed at reaction temperatures lower than 400 °C. A temperature higher than 425 °C led to films with voids between the crystallites. The bandgap of the optimized films was measured to be 0.89 eV and 0.83 eV using UV-VIS-NIR spectroscopy and spectroscopic ellipsometry measurements, respectively. This suggests the potential use of Cu3SbS4 as an absorber layer for thin film solar cells.

Graphical abstract: Synthesis and characterization of Cu3SbS4 thin films grown by co-sputtering metal precursors and subsequent sulfurization

Supplementary files

Article information

Article type
Paper
Submitted
06 Aug 2020
Accepted
27 Oct 2020
First published
31 Oct 2020
This article is Open Access
Creative Commons BY license

Mater. Adv., 2020,1, 3333-3338

Synthesis and characterization of Cu3SbS4 thin films grown by co-sputtering metal precursors and subsequent sulfurization

A. A. Rahman, E. Hossian, H. Vaishnav, J. B. Parmar, A. Bhattacharya and A. Sarma, Mater. Adv., 2020, 1, 3333 DOI: 10.1039/D0MA00574F

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