Super protective anti-bacterial coating development with silica–titania nano core–shells

Abstract

In the present study, we have developed an anti-bacterial as well as mechanically-strengthened super protective coating material, which can be used as a marine antifouling paint. In this research, silica, titania and silica–titania core–shell nanoparticles were individually prepared via sol–gel and peptization processes. The idea behind the synthesis of core–shell nanoparticles was to utilize the mechanical strength of silica and the antimicrobial property of TiO₂ together. These nanoparticles were characterized via dynamic light scattering, UV-Visible spectroscopy, X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy and X-ray photoelectron spectroscopy. Coating formulations were developed with two types of model binders, i.e., solvent-based polyurethane and water-based poly-acrylic, containing all nanoparticles individually at various concentrations for a better comparative study. These coating formulations were applied onto mild steel for anti-bacterial testing that was performed against Escherichia coli and Bacillus. The nanoparticle concentration was varied from 1% (wt) to 6% (wt). The best anti-bacterial result was obtained with 4% (wt) of silica–titania core–shell nanoparticles prepared via the peptization process among all the nanoparticles. The scratch testing was performed successfully using an Erichsen scratch tester; the formulated PU coating passed up-to 20 N load with good adhesion, impact resistance, flexibility and has shown satisfactory anti-corrosion performance.