Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations

Andressa Lunardi; Camila Nunes Cechin; Ernesto Schulz Lang; Roberta Cargnelutti; Nahum Ramirez Pineda; Paulo Cesar Piquini; Robert Alan Burrow; Sailer Santos dos Santos; Tanize Bortolotto; Bárbara Tirloni

doi:10.1039/D0NJ00343C

Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations†

Andressa Lunardi,^a Camila Nunes Cechin,^a Ernesto Schulz Lang,

^a Roberta Cargnelutti,

^a Nahum Ramirez Pineda,^a Paulo Cesar Piquini,^b Robert Alan Burrow,

^a Sailer Santos dos Santos,^a Tanize Bortolotto^a and Bárbara Tirloni

*^a

Author affiliations

* Corresponding authors

^a Departamento de Química, Universidade Federal de Santa Maria – UFSM, Laboratório de Materiais Inorgânicos – LMI, Santa Maria, RS, Brazil
E-mail: barbara.tirloni@ufsm.br

^b Departamento de Física, Universidade Federal de Santa Maria, Santa Maria, RS, Brazil

Abstract

Novel tetranuclear zinc compounds, [Zn₄(μ-SeO₃)₂(μ₄-SeO₃)₂(bipy)₄]·11H₂O (1) and [Zn₄(μ-SeO₃)₂(μ₄-SeO₃)₂(phen)₄]·9H₂O (2), which are the first examples of organically templated zinc selenite compounds containing closed-frameworks, have been synthesized via solvothermal processes. The compounds were characterized by spectroscopy, crystallographic methods and DFT calculations.

New Journal of Chemistry

Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations†

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Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations

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