Preparation of MOF catalysts and simultaneously modulated metal nodes and ligands via a one-pot method for optimizing cycloaddition reactions

Abstract

MOF catalysts were fabricated using a one-pot method that simultaneously adjusts the metal nodes and ligands. The pore environments, Lewis acids (LAs) and Brønsted acids (BAs), were controlled when BA groups were used to modify the ligands and monoacids were used to adjust the metal nodes. The catalysts exhibited remarkable catalytic performance in cycloaddition reactions.