Towards enhanced sodium storage of anatase TiO2via a dual-modification approach of Mo doping combined with AlF3 coating

Abstract

Recent studies on anatase TiO₂ have demonstrated its capability of performing as an anode material for sodium-ion batteries (SIBs) even though, due to poor conductivity, realistic applications have not yet been foreseen. In order to try to address this issue, herein, we shall introduce a cost effective and facile route based on the co-precipitation method for the synthesis of Mo-doped anatase TiO₂ nanoparticles with AlF₃ surface coating. The electrochemical measurements demonstrate that the Mo-doped anatase TiO₂ nanoparticles deliver an ∼40% enhanced reversible capacity compared to pristine TiO₂ (139.8 vs. 100.7 mA h g⁻¹ at 0.1 C after 50 cycles) due to an improved electronic/ionic conductivity. Furthermore, upon AlF₃ coating, the overall system can deliver a much higher reversible capacity of 178.9 mA h g⁻¹ (∼80% increase with respect to pristine TiO₂) with good cycling stability and excellent rate capabilities of up to 10 C. The experimental results indicate that the AlF₃ surface coating could indeed effectively reduce the solid electrolyte interfacial resistance, enhance the electrochemical reactivity at the surface/interface region, and lower the polarization during cycling. The improved performance achieved using a cost-effective fabrication approach makes the dually modified anatase TiO₂ a promising anode material for high-performance SIBs.