Improving efficiency and stability of colorful perovskite solar cells with two-dimensional photonic crystals

Abstract

Colorful solar cells have been much sought after because they can generate electricity and concurrently satisfy ornamentation purposes. Owing to their outstanding power conversion efficiency and flexibility in processing, perovskite solar cells (PSCs) have the great potential to become both efficient and aesthetically appealing. Here, we specially devise and fabricate two novel electron transport layers (ETLs) for PSCs with two-dimensional (2D) photonic crystal structures, namely the 2D inverse opal (IO) structured SnO₂ (IOS) and SnO₂–TiO₂ composite (IOST), using the template-assisted spin-coating method. The synergistic structure and material modifications to the ETLs lead to a number of unique features, including the remarkable electron transfer ability, vivid colors and good protection to the infiltrated perovskite films. Furthermore, the IOS and IOST ETLs are effectively incorporated into the CH₃NH₃PbI₃-based PSC devices that deliver the best efficiency of 16.8% with structural colors.