Layered MoS2 defect-driven in situ synthesis of plasmonic gold nanocrystals visualizes the planar size and interfacial diversity

Abstract

Current defect theories significantly guide broad research progress, whereas the recognition of defect status remains challenging. Herein, MoS₂ defect type, density and exposed state are visually identified with a reagent indicator of HAuCl₄. Mo-terminated defects spontaneously reduce [AuCl₄]⁻ anions and oxidized Mo species are dissociated. Consequently, MoS₂ edges guide the epitaxial branch of Au nanocrystals (NCs), followed by sequential growths at their planar defects. The size-evolution processes of LaMer growth and planar packages of the aggregative growth of Au/MoS₂ nanoseeds result in the occupation of Au atomic layers on heterostructures. Consequently, shell–core hybrids are presented with localized surface plasmon resonance characteristics. The mechanism is systematically explored via the discriminated performance of plasmonic characteristics of Au nanostructures on semiconducting MoS₂ substrates. With plasmonic identification, defect-associated size and interfacial diversities of MoS₂ are visually information-rich. Tunable morphologies and synergistic optical characteristics of plasmonic semiconductor heterostructures inspire many more applications through the edge and planar defects intrinsic in layered MoS₂.